Product ID:METHYLENE CHLORIDE URETHA GRADE
MSDS Date:12/07/1995
FSC:6810
NIIN:00-244-0290
MSDS Number: CGMFR

DOW CHEMICAL U S A

2030 DOW CENTER BARSTOW BLDG
MIDLAND, MI 48640
US

Emergency Phone: 517-636-4400

Info Phone: 517-636-4410

Cage: 71983

JEM SALES INC INCHEMCO DIV

ROME, GA 30165-2262 US

Telephone: 706-232-1709

Cage: 0AZD7

METHYLENE CHLORIDE (SARA 313) (CERCLA)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 98.4%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPYLENE OXIDE (SARA 302/313) (CERCLA)

CAS: 75-56-9

RTECS: TZ2975000

Fraction By Weight: 1.6%

OSHA PEL 100 PPM

ACGIH TLV: 20 PPM; 9596

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:ORAL RATS LD50 1500-2500MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE MODERATE EYE IRRITATION.
SKIN:PROLONGED OR REPEATED EXPOSURE MAY CAUSE SKIN IRRITATION.
INGESTION:SWALLOWING LARGE AMOUNTS MAY CAUSE INJURY. INHALATION:IN
CONFINED OR POORLY VENTILATED AREAS, VAPORS CAN READILY
ACCUMULATED AND CAN CAUSE UNCONSCIOUSNESS AND DEATH.
Explanation of Carcinogenicity:PER MSDS:PER OSHA 29CFR1910.1200 LISTED
AS POTENTIAL CARCINOGEN BY IARC/NTP.
Effects of Overexposure:EYE-MAY CAUSE PAIN. SKIN-MAY CAUSE BURNS,
DRYING OR FLAKING OF SKIN. INHALATION-CAN CAUSE DIZZINESS,
DRUNKENNESS, CARDIAC ARRYTHMIAS (IRREGULAR HEARTBEATS)
UNCONSCIOUSNESS AND DEATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:IRRIGATE W/FLOW WATER IMMEDIATELY FOR 15MINS. SEE
PHYSICIAN. SKIN:WASH OFF IN FLOW WATER/SHOWER. INGEST:DON'T INDUCE
VOMIT. CALL A PHYSICIAN &/OR TRANSPORT TO EMERGENCY FACILITY
IMMEDIATELY. INHAL E:REMOVE TO FRESH AIR. IF NOT BREATH GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN SHOULD BE
ADMINISTERED BY QUALIFIED PERSONNEL. CALL A PHYSICIAN OR TRANSPORT
TO A MEDICAL FACILITY.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:14
Upper Limits:22
Extinguishing Media:WATER FOG,FINE SPRAY,CARBON DIOXIDE,CHEMICAL,FOAM.
WATER FOG APPLIED GENTLY MAY BE USED AS BLANKET FOR FIRE
EXTINGUSHMEN
Fire Fighting Procedures:KEEP PEOPLE AWAY. ISOLATE AREA/DENY ENTRY.
CONTAIN FIRE RUN-OFF IF POSSIBLE. WEAR POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:CONTAINER MAY VENT &/OR RUPTURE DUE TO
FIRE. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL A LONG DISTANCE &
ACCUMULATE IN LOW LYING AREAS.

Spill Release Procedures:FOR LARGE SPILLS: CONTAIN LIQUID; TRANSFER TO
PROPERLY LABELED CLOSED METAL CONTAINER. FOR SMALL SPILLS: MOP OR
SOAK UP IMMEDIATELY. PLACE IN PROPERLY LABELED METAL CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINERS IN TIGHTLY CLOSED
CONTAINERS WHEN NOT IN USE. STORE IN A DRY PLACE.
Other Precautions:DON'T STORE IN AL, ZN, AL ALLOYS, PLASTICS. PRODUCT
DENSER THATN WATER. CONTAIN LIQ TO PREVENT CONTAMIN OF SOIL,
SURFACE WATER, GROUND WATER. SARA TITLE III SEC 313 CHEMS.

Respiratory Protection:MAINTAIN ATM LEVELS BEL EXPO GUIDELINE.WHEN RESP
PROTECTION REQUIRED USE APPROVED AIR-PURIFYING/POSITIVE-PRESSURE
SUPPLIED- AIR RESP DEPENDING ON POT AIRBORNE CONC.EMERG/EXPO
GUIDLINE EXCEEDED +PRESSU RE SCBA/AIRLINE W/AUX SCBSUPPLIED.
Ventilation:PROVIDE GEN/LOC EXHAUST VNETILATION TO CONTROL AIRBORNE
LEVELS BEL EXPOSURE GUIDELINES. LETHAL CONC MAY EXIST IN AREAS.
Protective Gloves:SPECIFIC ITEM DEPEND ON OPERATION.
Eye Protection:SAFETY GLASSES,FULL-FACE RESPIRATOR.
Other Protective Equipment:USE PPE IMPERVIOUS TO MATERIAL. SELECTION
DEPEND ON OPERATION.
Work Hygienic Practices:DON'T EAT/DRINK/SMOKE IN WORK AREA. REMOVE
CONTAMINATION CLOTHING IMMEDIATELY ;LAUNDER CLOTH BEFORE REUSE.
Supplemental Safety and Health
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:355MM
Vapor Density:2.93
Spec Gravity:1.320
pH:NP
Evaporation Rate & Reference:NP
Solubility in Water:2G/100G @25C.
Appearance and Odor:COLORLESS LIQUID, IRRITATING ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
METALS (AL, MG, K, NA, ZN POWEDRS). AMINES, STRONG BASES,
STRONGOXIDIZERS, PROLONG CONTACT W/OR STORAGE IN AL/AL ALLOYS.
Stability Condition to Avoid:AVOID DIRECT SUNLIGHT/ULTRAVIOLET SOURCES,
OPEN FLAMES, WELD ARC, HIGH TEMP SOURCES. HIGH ENERGY SOURCES
DEGRADE MATERLS
Hazardous Decomposition Products:SMOKE CONTAINS ORIGINAL MATERIAL,
UNIDENTIFIED TOXIC &/OR IRRIT COMPDS.HYDROGEN CHLORIDE.TRACE AMTS
OF PHOSGENE CHLORINE

Waste Disposal Methods:DON'T DUMPT INTO SEWERS/GROUND/BODY OF
H2O.ICW/ALL FED/STATE/PROVIN/LOC LAWS/REGS.WASTE
CHARACTER/COMPLINACE W/APPLICA LAWS WASTE GENERATOR
RESPONSIBILITY.UNUSED/UNCONTAM PROD:SEND TO LIC,PERMITT RECY
CLER,RECLAIMER,INCINER,OTHER THERM DESTRUCTION DEV

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.